Ionic Equilibria in Analytical Chemistry

Jean-Louis Burgot

Buku ini diterbitkan oleh Springer tahun 2012. Cakupan 762 halaman.

Daftar isi:

Part I. General Considerations 

• Solvents—Composition of Solutions,  3
•  Thermodynamics and Equilibrium, 13
•  Activities and Activity Coefficients, 37

Part II. Acids and Bases Equilibria—Analytical Applications 

• Definitions of Acids and Bases: Strength of Acids and Bases, 51
•  Calculations of pH Values in Aqueous Solutions, 77
•  Buffer Solutions, 107
•  Some General Points Concerning Titrations, 119
•  Neutralization or Acid-Base Indicators, 127
•  Acid–Base Titration Curves, 135
•  Acid–Base Titrations: Further Theoretical Studies, 157
•  Acid–Base Reactions and Chemical Analysis, 169

Part III. Redox Phenomena and Analytical Applications
  

• Generalities on Oxidation-Reduction, 193
•  Redox Reactions and Electrochemical Cells, 205
•  Predicting Redox Reactions, 229
•  Predicting Redox Reactions by Graphical Means, 247
•  Calculating Equilibrium Potentials of Solutions Containing Several Redox Couples, 265
•  A Study of Some Redox Titration Curves, 285
•  Oxidoreductimetry: Direct and Indirect Iodometries, 313
•  Iodometry in Alkaline Medium, Iodatometry, Periodimetry, and Bromometry, 347
•  Oxidizations with Permanganate, Dichromate, and Ceric Ions Some Titration Methods Involving a Reduction Reaction, 377
•   Some Applications of Redox Reactions in Qualitative Analysis, 405

Part IV. Complexation Reactions—Analytical Applications

• General Definitions Concerning Complexes Rules of Nomenclature and Writing, 423
•  Some Elements Concerning the Chemistry of Complexes, 429
•  Stability of Complexes: Some Elements Concerning the Kinetics of Their Formation, 439
•  Superimposition of Varied Equilibria to Complexation Equilibria, 461
•  Conditional Stability Constants, 485
•  Complexometry I: Mercurimetry (Votocek–Dubsky’s Method), 503
•  Complexometry II: Titrations with EDTA, 513
•  Complexometry III: Metal Cation Indicators and Types of EDTA Titrations, 525
•  Applications of the Formation of Complexes in Inorganic Analysis, 543

Part V. Precipitation Phenomena—Analytical Applications

• Applications of the Formation of Complexes in Organic Analysis, 575
•  Intrinsic, Ionic, and Total Solubilities; Solubility Product and Precipitation, 609
•  Dependence of the Solubility on the Solution’s Ionic Strength and on the Presence of Common Ions: Superimposition of Several Precipitation Equilibria, 619
•  Solubility and pH, 633
•  Precipitation and Complexation, 659
•  Theoretical Study of Some Precipitation Titration Curves, 679
•  Titrimetric Methods Involving a Precipitation, 689
•  Gravimetry by Precipitation, 705
•  Some Applications of the Precipitation Phenomenon in Inorganic and Organic Qualitative and Quantitative Analysis, 721

Appendix  A - F, 743-753

Index, 765

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